碌潞陆貌鲁卢驴矛脣脵脪潞脧脿脡芦脝脳脪脟Prominenece UFLC录貌碌楼陆茅脡脺
碌潞陆貌 鲁卢驴矛脣脵脪潞脧脿脡芦脝脳脪脟 Prominenece UFLC脢鹿脫脙卤锚脳录虏驴录镁拢卢驴脡脪脭脥卢脢卤脗煤脳茫脩脨戮驴脠脣脭卤麓芦脥鲁路脰脦枚潞脥赂脽脣脵路脰脦枚碌脛脨猫脟贸拢卢脪虏驴脡脪脭脰搂鲁脰赂脽麓茂85隆忙碌脛虏脵脳梅脦脗露脠拢卢麓脫露酶脢鹿赂眉碌脥脩鹿脕娄脧脗碌脛驴矛脣脵路脰脦枚鲁脡脦陋驴脡脛脺拢卢脥卢脢卤赂脙脪脟脝梅脤氓脧脰鲁枚碌脛路脰脦枚脨脭脛脺潞脥脥篓脕驴脣庐脝陆录麓脢鹿脢脟脭脷赂眉掳潞鹿贸碌脛脪脟脝梅脜盲脰脙脡脧脪虏虏禄露脿录没隆拢
碌潞陆貌鲁卢驴矛脣脵脪潞脧脿脡芦脝脳脪脟Prominenece UFLC脧锚脧赂陆茅脡脺
碌潞陆貌鲁卢驴矛脣脵脪潞脧脿脡芦脝脳脪脟Prominenece UFLC脢鹿脫脙卤锚脳录虏驴录镁拢卢驴脡脪脭脥卢脢卤脗煤脳茫脩脨戮驴脠脣脭卤麓芦脥鲁路脰脦枚潞脥赂脽脣脵路脰脦枚碌脛脨猫脟贸拢卢脪虏驴脡脪脭脰搂鲁脰赂脽麓茂85隆忙碌脛虏脵脳梅脦脗露脠拢卢麓脫露酶脢鹿赂眉碌脥脩鹿脕娄脧脗碌脛驴矛脣脵路脰脦枚鲁脡脦陋驴脡脛脺拢卢脥卢脢卤赂脙脪脟脝梅脤氓脧脰鲁枚碌脛路脰脦枚脨脭脛脺潞脥脥篓脕驴脣庐脝陆录麓脢鹿脢脟脭脷赂眉掳潞鹿贸碌脛脪脟脝梅脜盲脰脙脡脧脪虏虏禄露脿录没隆拢
碌潞陆貌鲁卢驴矛脣脵脪潞脧脿脡芦脝脳脪脟Prominenece UFLC脪脟脝梅脤脴碌茫
驴矛脣脵路脰脦枚脳梅脦陋脰脴脪陋录录脢玫驴脦脤芒脪禄脰卤脪脭脌麓露录脭脷脢鹿脫脙拢卢碌芦掳茅脣忙LCMS碌脛脩赂脣脵脝脮录掳拢卢脤谩赂脽脨脭录脹卤脠鲁脡脦陋脝脠脭脷脙录陆脼碌脛脦脢脤芒拢卢鲁脡脦陋脕脣录脫陆么驴矛脣脵禄炉碌脛脰脴脪陋脪貌脣脴隆拢驴矛脣脵路脰脦枚录麓脣玫露脤路脰脦枚脢卤录盲拢卢脥篓鲁拢脥篓鹿媒脣玫露脤脡芦脝脳脰霉禄貌脤谩赂脽脕梅露炉脧脿碌脛脕梅脕驴脌麓麓茂碌陆脛驴碌脛隆拢碌芦脢脟拢卢脢鹿脫脙鲁拢脫脙碌脛脕拢戮露5娄脤m碌脛脤卯鲁盲脰霉拢卢脢鹿脫脙脠脦潞脦路陆路篓路脰脌毛脨脭脛脺露录禄谩脙梅脧脭脧脗陆碌拢卢麓脫露酶脢鹿驴矛脣脵禄炉脢搂脠楼脪芒脪氓隆拢脪貌麓脣拢卢脪脭脧脗脕陆脰脰路陆路篓碌脙脪脭路垄脮鹿拢潞
拢篓脪禄拢漏脢鹿脫脙脨隆脕拢戮露碌脛脤卯脕脧
脥篓鹿媒脮芒赂枚路陆路篓陆芦脢鹿驴矛脣脵路脰脌毛鲁脡脦陋驴脡脛脺隆拢碌芦脢脟拢卢脫脡脫脷脡芦脝脳脰霉脌茂脕梅露炉脳猫脕娄碌脛脭枚录脫拢卢脪脟脝梅赂梅虏驴录镁潞脥脡芦脝脳脰霉脣霉鲁脨脢脺碌脛脩鹿脕娄脪虏陆芦脧脭脰酶碌脴脭枚录脫隆拢
拢篓露镁拢漏赂脽脦脗路脰脌毛
陆脧赂脽碌脛脦脗露脠驴脡脪脭录脫脣脵脦茂脰脢碌脛脌漏脡垄拢卢脥卢脢卤驴脡脪脭录玫脨隆脡芦脝脳脰霉脌茂碌脛脕梅露炉脳猫脕娄拢卢脪虏脢鹿碌脙驴矛脣脵路脰脌毛鲁脡脦陋驴脡脛脺隆拢赂脽脦脗路脰脦枚脭脷陆碌碌脥脰霉脩鹿路陆脙忙潞脺脫脨脨搂拢卢碌芦脢脟赂脽脦脗脪媒脝冒脡芦脝脳脰霉碌脛脕脫禄炉隆垄碌录脰脗脩霉脝路路脰陆芒碌脠虏禄脳茫脭脷脫娄脫脙脢卤脨猫脪陋脪媒脝冒脳垄脪芒隆拢
脦陋脕脣陆芒戮枚卤鲁脩鹿脦脢脤芒拢卢赂脛陆酶脕脣鲁脨脩鹿脛脺脕娄碌脛脳篓脫脙脪脟脝梅碌脙碌陆路垄脮鹿拢卢脮芒脌脿脪脟脝梅脥篓鲁拢卤脠陆脧掳潞鹿贸隆拢脠禄露酶拢卢脮芒脨漏脳篓脫脙脪脟脝梅脭脷陆酶脩霉脨脭脛脺潞脥脕茅脙么露脠路陆脙忙虏禄碌脙虏禄脳枚鲁枚脥脳脨颅隆拢虏垄脟脪拢卢脤卯脕脧鹿媒脫脷脧赂脦垄禄炉碌脛脤卯鲁盲脰霉拢卢露脭脫脷脫虏录镁碌脛脪陋脟贸赂脽拢卢脢鹿脫脙脮芒脰脰脡芦脝脳脰霉驴陋路垄碌脛路脰脦枚路篓脦镁脡眉脕脣脥篓脫脙脨脭隆拢脪貌麓脣拢卢脠莽鹿没掳脩脮芒脰脰脪脟脝梅脫脙脫脷鲁拢鹿忙碌脛HPLC路脰脦枚脰脨拢卢脝盲脨搂脗脢陆芦禄谩卤盲碌脥隆拢鲁卢驴矛脣脵脪潞脧脿脡芦脝脳脪脟Prominence脰搂鲁脰驴矛脣脵路脰脌毛
鲁卢驴矛脣脵脪潞脧脿脡芦脝脳脪脟Prominence脢鹿脫脙卤锚脳录虏驴录镁拢卢驴脡脪脭脥卢脢卤脗煤脳茫脩脨戮驴脠脣脭卤麓芦脥鲁路脰脦枚潞脥赂脽脣脵路脰脦枚碌脛脨猫脟贸拢卢脪虏驴脡脪脭脰搂鲁脰赂脽麓茂85隆忙碌脛虏脵脳梅脦脗露脠拢卢麓脫露酶脢鹿赂眉碌脥脩鹿脕娄脧脗碌脛驴矛脣脵路脰脦枚鲁脡脦陋驴脡脛脺拢卢脥卢脢卤赂脙脪脟脝梅脤氓脧脰鲁枚碌脛路脰脦枚脨脭脛脺潞脥脥篓脕驴脣庐脝陆录麓脢鹿脢脟脭脷赂眉掳潞鹿贸碌脛脪脟脝梅脜盲脰脙脡脧脪虏虏禄露脿录没隆拢
鲁卢驴矛脣脵脪潞脧脿脡芦脝脳脪脟Prominence UFLC脥篓鹿媒脪脭脧脗脤脴脨脭脰搂鲁脰驴矛脣脵路脰脦枚
1隆垄脨隆脰霉鹿脺潞脥脨隆脤氓禄媒碌脛脕梅脥篓鲁脴陆碌碌脥脕脣脰霉脥芒路氓脮鹿驴铆脨搂脫娄隆拢
2隆垄脢鹿脫脙2.2娄脤m驴脜脕拢麓贸脨隆碌脛脡芦脝脳脰霉Shim-pack XR-ODS隆拢
Shim-pack XR-ODS脢脟驴录脗脟脡脧脢枚脤卯脕脧脧赂脦垄禄炉碌脛脦脢脤芒拢卢麓脫路脰脌毛脨搂脗脢潞脥脩鹿脕娄碌脛鹿脴脧碌脰脨脟脡脙卯脮脪碌陆脝陆潞芒拢卢驴脡脤谩赂脽禄貌脦卢鲁脰路脰脌毛脨搂鹿没碌脛脥卢脢卤脣玫露脤路脰脦枚脢卤录盲碌脛脨脗脪禄麓煤驴矛脣脵路脰脦枚脫脙脡芦脝脳脰霉隆拢
Chromatographic conditions; column: described above, mobile phase: water/acetonitrile (3/7,v/v), flow rate: described above, temperature: 40隆忙, detection: absorbance at 245 nm, sample volume: 4娄脤L(XR-ODS), 10娄脤L(VP-ODS).
Peaks; 1: actophenone, 2: propiophenone, 3: butyrophenone, 4: balenophenone, 5: hexanophenone, 6: heptanophenone, 7: octanophenone.
3隆垄Prominence SIL-20A脳脭露炉陆酶脩霉脝梅脢碌脧脰10脙毛脰脫10娄脤l碌脛鲁卢驴矛脣脵陆酶脩霉隆拢
Chromatographic conditions; column: Shim-pack XR-ODS(3mm i.d.隆脕30mm, 2.2娄脤m), mobile phase: water/acetonitrile(4/6 to 2/8 in 0.4 min, convex gradient), flow rate: 3mL/min, temperature: 80隆忙, detection: absorbance at 245 nm, sample volume: 4娄脤L(each 800 nm ol),.0.1 min delayed injection.
Peaks; 1: actophenone, 2: propiophenone, 3: butyrophenone, 4: balenophenone, 5: hexanophenone, 6:heptanophenone, 7:octanophenone.
4隆垄脰搂鲁脰赂脽麓茂85隆忙碌脛赂脽脦脗路脰脦枚隆拢
脦脗露脠脫毛驴矛脣脵路脰脦枚拢潞脣忙脳脜脰霉脦脗脡媒赂脽拢卢脌铆脗脹脣镁掳氓脢媒脭枚录脫拢卢脰霉脨搂脭枚赂脽拢卢脰霉脩鹿陆碌碌脥隆拢
Chromatographic conditions;
mobile phase:隆隆water/acetonitrile (3/7, v/v),
detection: absorbance at 245 nm.
Peaks:1:卤陆脪脪脥陋 2: 卤陆卤没脥陋 3:卤陆露隆脥陋 4:卤陆脦矛脥陋 5:卤陆录潞脥陋 6:卤陆赂媒脥陋 7:卤陆脨脕脥陋
脦脗露脠露脭禄炉潞脧脦茂碌脛脫掳脧矛拢潞赂脽脦脗路脰脦枚脭脷陆碌碌脥脰霉脩鹿路陆脙忙潞脺脫脨脨搂拢卢碌芦脢脟赂脽脦脗脪媒脝冒脡芦脝脳脰霉碌脛脕脫禄炉隆垄碌录脰脗脩霉脝路路脰陆芒碌脠虏禄脳茫脭脷脫娄脫脙脢卤脨猫脪陋脪媒脝冒脳垄脪芒隆拢赂脽脦脗路脰脦枚脰禄脢脟脳梅脦陋驴矛脣脵路脰脦枚碌脛赂篓脰煤脢脰露脦录脫脪脭脭脣脫脙隆拢
5隆垄戮脽卤赂赂脽虏脡脩霉脝碌脗脢碌脛录矛虏芒脝梅拢卢驴脡脪脭脢碌脧脰驴矛脣脵碌脛脢媒戮脻禄帽脠隆露酶虏禄禄谩露陋脢搂脨脜脧垄隆拢
6隆垄脳篓脙脜碌脛脡芦脝脳路陆路篓脳陋禄禄脠铆录镁拢卢脢鹿鲁拢鹿忙脡芦脝脳脤玫录镁脳陋禄禄脦陋UFLC脤玫录镁录貌碌楼脪脳脨脨拢卢卤拢脰陇路脰脦枚路陆路篓碌脛脥篓脫脙脨脭隆拢
驴矛脣脵路脰脦枚碌脛脰脴脧脰脨脭
脭脷驴矛脣脵路脰脌毛脰脨脪陋脠隆碌脙鲁脡路脰卤拢脕么脢卤录盲碌脛脰脴脧脰脨脭脪陋卤脠鲁拢鹿忙路脰脦枚脰脨赂眉录脫脌搂脛脩隆拢卤拢脕么脢卤录盲碌脛脰脴脧脰脨脭拢篓RSD拢漏潞脥脢卤录盲碌脛脝陆路陆赂霉鲁脡路麓卤脠脭枚麓贸拢卢脣霉脪脭脨猫脪陋卤脠鲁拢鹿忙路脰脦枚赂眉脦陋脩脧赂帽碌脛脣脥脪潞脨脭脛脺隆拢Prominence UFLC驴脡脪脭卤拢脰陇脣脥脪潞路脰卤忙脗脢 3nL/min碌脛脦垄鲁氓鲁脤脣脥脪潞隆垄脤脻露脠脣脥脪潞脢卤驴脴脰脝脧矛脫娄脦陋0.1脙毛碌脛脳驴脭陆脣脥脪潞脛脺脕娄拢卢驴脡脪脭路垄禄脫录芦脦陋脫脜脭陆碌脛卤拢脕么脢卤录盲脰脴脧脰脨脭隆拢
脢虏脙麓脢脟赂脽脥篓脕驴拢驴
驴矛脣脵脪潞脧脿脡芦脝脳碌脛脛驴卤锚戮脥脢脟赂脽脥篓脕驴拢卢脪虏戮脥脢脟脣碌脙驴脤矛禄貌脙驴脨隆脢卤脫脨赂眉露脿碌脛脩霉脝路卤禄路脰脦枚隆拢脦陋脕脣脢碌脧脰赂脽脥篓脕驴拢卢虏禄陆枚脪陋脣玫露脤碌楼赂枚脩霉脝路路脰脦枚脢卤录盲拢卢露酶脟脪脮没赂枚脩颅禄路陆酶脩霉潞脥路脰脦枚脢卤录盲脪虏卤脴脨毛脫脜禄炉隆拢脳路脟贸驴矛脣脵禄炉碌脛卤戮脪芒虏禄陆枚脢脟脣玫露脤路脰脦枚脢卤录盲拢卢露酶脟脪脢脟脣玫露脤路脰脦枚脰脺脝脷隆拢Prominence UFLC碌脛脩霉脝路脳垄脠毛脣脵露脠脦陋10脙毛拢卢脢鹿碌脙路脰脦枚脰脺脝脷碌脙脪脭麓贸脦陋脣玫露脤隆拢
鲁卢驴矛脣脵脪潞脧脿脡芦脝脳脪脟Prominence UFLC脫娄脫脙脢碌脌媒
PTC脩脺脡煤掳卤禄霉脣谩碌脛UFLC路脰脦枚
掳卤禄霉脣谩路脰脦枚脫脨脕陆脰脰录矛虏芒路陆路篓拢卢脝盲脪禄脢脟脢鹿脫脙脌毛脳脫陆禄禄禄脡芦脝脳脰霉路脰脌毛脰庐潞贸拢卢陆酶脨脨脩脺脡煤禄炉脭脵录矛虏芒碌脛脰霉潞贸脩脺脡煤禄炉路篓拢卢脕铆脪禄脰脰脢脟脧脠脩脺脡煤禄炉潞贸拢卢脢鹿脫脙路麓脧脿脡芦脝脳脰霉陆酶脨脨路脰脌毛碌脛脰霉脟掳脩脺脡煤路篓隆拢麓脫驴矛脣脵路脰脦枚碌脛陆脟露脠驴录脗脟拢卢脰霉脟掳脩脺脡煤禄炉路篓脨脨脰庐脫脨脨搂隆拢脭脷麓脣拢卢脢鹿脫脙Shim-pack XR-0DS脪脭赂眉露脤碌脛脢卤录盲陆酶脨脨脕脣掳卤禄霉脣谩路脰脦枚隆拢
脢鹿脫脙脪矛脕貌脟猫脣谩卤陆玫楼陆酶脨脨脩脺脡煤禄炉隆拢脰霉潞贸脩脺脡煤路篓脢卤脨猫脪陋1脨隆脢卤拢卢脰霉脟掳脩脺脡煤禄炉路篓脢鹿脫脙鲁拢鹿忙脡芦脝脳脰霉脢卤脨猫脪陋25路脰脰脫碌脛路脰脦枚驴脡脣玫露脤脰脕4路脰脰脫隆拢
露脿禄路路录脤镁(PAHs)碌脛UFLC路脰脦枚
PAHs脢脟脪禄脰脰脜脨露脧鲁碌脕戮碌脠路脧脝酶脦脹脠戮麓贸脝酶禄路戮鲁鲁脤露脠碌脛禄炉脩搂脦茂脰脢隆拢PAHs戮脽脫脨脟驴脰脗掳漏脨脭拢卢脣霉脪脭脮芒脨漏脦茂脰脢碌脛麓贸脝酶录脿虏芒脢脟脰脴脪陋碌脛虏芒露篓脧卯脛驴隆拢PAHs脧脭脢戮脟驴脫芦鹿芒拢卢驴脡脪脭脌没脫脙脫芦鹿芒录矛虏芒脝梅陆酶脨脨赂脽脕茅脙么路脰脦枚隆拢
露脭脫脷麓脣10脰脰PAHs碌脛路脰脦枚拢卢脭脷虏禄脣冒脢搂路脰脌毛脳麓脤卢脧脗拢卢脧脿露脭脫脷鲁拢鹿忙LC (路脰脦枚脢卤录盲50路脰脰脫)拢卢UFLC脢碌脧脰脕脣10卤露脣脵露脠碌脛驴矛脣脵禄炉路脰脦枚拢篓路脰脦枚脢卤录盲5路脰脰脫拢漏隆拢
脡芦脣脴碌脛UFLC路脰脦枚
脤铆录脫脭脷脢鲁脝路脰脨碌脛脡芦脣脴脫脨潞脧鲁脡禄炉潞脧脦茂潞脥脤矛脠禄禄炉潞脧脦茂拢卢脮芒脨漏脡芦脣脴脣庐脠脺脨脭赂脽拢卢露脿脫脙HPLC陆酶脨脨路脰脦枚隆拢碌芦脭脷露脿赂枚脡芦脣脴脳茅潞脧脢鹿脢卤拢卢脥卢脢卤路脰脦枚脣霉脨猫脢卤录盲鲁陇隆拢脭脷麓脣卤铆脢戮脢鹿脫脙Shim-pack XR-ODS鲁卢驴矛脣脵LC陆酶脨脨碌脛脡芦脣脴脥卢脢卤路脰脦枚脌媒隆拢12脰脰鲁脡路脰脡芦脣脴碌脛脥卢脢卤路脰脦枚碌脛陆谩鹿没脠莽脧脗脮脜脡芦脝脳脥录隆拢脢鹿脫脙鲁拢鹿忙LC脣霉脨猫路脰脦枚脢卤录盲脦陋50路脰脰脫拢卢露酶脢鹿脫脙鲁卢驴矛脣脵LC拢卢脭录6路脰脰脫卤茫陆谩脕脣路脰脦枚隆拢
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